Product ID:VN 5099 WHITE GELCOAT, VN 05099
MSDS Date:01/01/1993
FSC:6850
NIIN:00N040310
MSDS Number: BSFXM

FERRO CORP

1301 N FLORA ST
PLYMOUTH, IN 46563-1344
US

Emergency Phone: 219-935-5131

Info Phone: 219-935-5131

Preparer: K.K.R.

Cage: 7L115

FERRO CORP

PLYMOUTH, IN 46563-1344 US

Telephone: 219-935-5131

Cage: 7L115

OVERWHELMED AT HIGH LEVELS & CONTRIBUTED TO

CAN CAUSE ASPIR OF SOLV INTO LUNGS, WHICH

SEPARATELY INTO PROD. NEVER MIX PROMOTORS &

PRODUCTS RESIDUES (VAPORS, LIQUID OR SOLID), ALL

GLOVES. REPLACE EVERY 4 HOURS OR AS OFTEN AS

4.5 @ 68F.

CAS: 100-42-5

RTECS: WL3675000

Fraction By Weight: 25.20%

OSHA PEL 50 PPM; 100 STEL

ACGIH TLV: 50 PPM; 100 STEL, S

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

TITANIUM DIOXIDE.

CAS: 13463-67-7

RTECS: XR2275000

Fraction By Weight: 10.00%

OSHA PEL 10 MG/M3 TDUST

ACGIH TLV: 10 MG/M3 TDUST

FIBROSIS. ONE STUDY OF TITANIUM DIOXIDE REVEALED

AT 250 MG/M3. THIS EFT WAS NOT OBSERVED AT LOW

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:YES OSHA:NO
Health Hazards Acute and Chronic:EYES: CAN CAUSE SEVERE EYE IRRIT
W/BURNING SENSATION. SKIN: MAY CAUSE SKIN IRRIT, DERMAT. SKIN
ABSORP: CAN OCCUR TO SIGNIFICANTLY INCREASE OVEREXP FROM OTHER
ROUTES OF ENTRY. INHAL: CAN CAUSE RESP IRR IT. HIGH LVLS CAN CAUSE
ANESTH EFTS/CNSDEPRESS. MAY BE FATAL @ 10,000 PPM. MAY CAUSE
ALLERGIC RESP (EFTS OF OVEREXP)
Explanation of Carcinogenicity:STYRENE: IARC: CLASS 2B (VP;7, P345,
1987).
Effects of Overexposure:HLTH HAZ:RXNS, MECH IRRIT. EXCESS EXPOS TO TALC
MAY CAUSE BRONCHITIS. INGEST: HARMFUL/FATAL IF INGEST. CAUSES GI
IRRIT & WILL CONTRIBUTE TO SYSTEMIC EFTS. CHRONIC: PRLNGD/RPTD SKIN
CONT MAY CAUSE DERM AT &/ALLERGIC RXN. PRNGD EXPOS CAN CAUSE NAUS,
HDCH, VOMIT, LOSS OF APPETITE, WEAKNESS.PRLG EXPOS TO EXCESS (SUPP
DATA)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:EYES: IMMED FLUSH WITH LOTS OF WATER FOR AT LEAST 15 MINUTES
& GET PROMPT MED ATTN. SKIN: WASH THOROUGHLY. REMOVE VICTIM FROM
EXPOS TO WELL VENT AREA. MAKE COMFORTABLY WARM BUT NOT HOT. USE
OXYGEN/ART F RESP AS REQD. SEE MD IF IRRIT PERSISTS. INGEST: CALL
MD IMMED. ONLY INDUCE VOMIT AT INSTRUCTIONS OF DOCTOR. NEVER GIVE
ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. NOTE TO MD: VOMIT (ING
6)

Flash Point Method:TCC
Flash Point:85.0F,29.4C
Lower Limits:1.1%
Upper Limits:6.1%
Extinguishing Media:FOAM, CO*2, DRY CHEMICAL.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL
PROTECTIVE EQUIPMENT.
Unusual Fire/Explosion Hazard:HIGHLY FLAMM. CAN POLYMERIZE WHEN HEATED.
SEALED CNTNRS CAN RUPTURE EXPLOS WHEN HEATED. COMBUST CAN PRDCE TOX
GASES. TREAT AS OIL FIRE. VAPS ARE (SUPP DATA)

Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. VENT AREA &
MAINTAIN VENT. USE ALL DESCRIBED PROTECTIVE MEASURES & EQUIPMENT.
USE ABSORBANT MATERIAL, SUCH AS CLAY OR SAND, TO COLLECT & CONTAIN
FOR SALVAGE & DISPOSAL.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:STORE IN CLSD CNTNRS AWAY FROM
SUNLIGHT, HEAT, FLAMES & SPARKS. STORE BELOW 100F, 60-80F
PREFERRED. DO NOT CUT, PUNCTURE/WELD ON/NEAR CNTNR.
Other Precautions:DO NOT STORE NEAR FOOD/FEED. AVOID IMPROPER ADDITION
OF PROMOTER & CATALYST. CONSULT PROD BULLETIN. PROMOTERS (METAL
ORGANICS SUCH AS COBALT/ANALINE TYPE) & CATALYST (ORG PEROXIDE
TYPE) USED W/PROD SH LD ALWAYS BE PREMIXED (ING 7)

Respiratory Protection:IN THE ABSENCE OF PROPER VENTILATION USE
NIOSH/MSHA APPROVED RESPIRATOR.
Ventilation:VENT TO MAINTAIN EXPOS BELOW PUBLISHED EXPOS LIMITS. USE
EXPLOSION PROOF MOTORS & WIRING.
Protective Gloves:NEW IMPERVIOUS (RUBBER,NITRILE)(ING 9)
Eye Protection:ANSI APRV CHEM WORK GOGG .
Other Protective Equipment:SAFETY SHOWERS & EYE WASH STATION WITHIN 10
SECONDS OF WORK STATION. WHERE SPLASH CAN OCCUR, USE AN APRON.
Work Hygienic Practices:WASH HANDS BEFORE EATING & SMOKING.
Supplemental Safety and Health
EXPLO HAZ: HVR/AIR, CAN TRAVEL ALONG GROUND/THRU VENT SYSTEMS & BE
IGNIT BY SPARKS,FLAMES/STATIC. WATER MAY BE USED TO KEEP FIRE-EXPOS
CNTNRS COOL UNTIL FIRE IS OUT. EFTS OF OVEREXP: QTYS OF TALC CAN
RSLT IN SCARRING OF LUNGS OR COVERING OF LUNGS. GROSSLY EXCESS &
PRLG EXPOS TO TITANIUM DIOXIDE MAY LEAD TO PULM (ING 3)

Boiling Pt:B.P. Text:>295F,>146C
Vapor Density:HVR/AIR
Spec Gravity:1.3 (H*2O=1)
Evaporation Rate & Reference:SLOWER THAN ETHER
Solubility in Water:NONE
Appearance and Odor:LIQUID WITH STYRENE ODOR.

Stability Indicator/Materials to Avoid:YES
STRONG ACIDS, PEROXIDES & OTHER OXIDIZING AGENTS.
Stability Condition to Avoid:CONSIDERED STABLE AT ROOM TEMPERATURE.
Hazardous Decomposition Products:OXIDES OF ALUMINUM, CARBON & TITANIUM;
INCOMPLETELY BURNED HYDROCARBONS
Conditions to Avoid Polymerization:SUNLIGHT, HEAT, FLAMES, SPARKS,
CONTAMINATION, PROLONGED STORAGE ABOVE 100F.

Waste Disposal Methods:PACKAGE IN DOT APPROVED CONTAINERS & TRANSPORT
TO AN EPA APPROVED TREATMENT, STORAGE & DISPOSAL FACILITY. DISPOSE
OF IN ACCORDANCE WITH LOCAL, STATE & FEDERAL REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.